Software used
Jade v6.1 (Materials Data Inc)

SMRR-1
minerals datafile (ICDD set 51 - 2001)

phases positively identified
Siderite FeCO3
gormanite Fe3Al4(PO4)4(OH)6.2H2O
quartz SiO2
fluorapatite Ca5(PO4)3F

possible lepidcrocite (else unidentified line at 6.24A)
unidentified minors possible, cf. 5.43A, 4.16A

SMRR-2
inorganic datafile (ICDD set 51)
also matches in organic datafile (ICDD set 51)
also matches in zeolite datafile (ICDD set 51)

phases positively identified
octadecasil - silicon oxide quinuclidine fluoride (or variant) 
cell edges do not agree (a=9.08,c=13.45 against 9.194, 13.396 expected) 

some lines remain. Unindexed lines from octadecasil? another phase?
Intensities also not good match.
 

SMRR-3
phamaceutical datafile (ICDD set 51)

no positive result - I lack the experience and knowledge.


SMRR-4
inorganic datafile

phases positively identified
lead oxide PbO
lead oxide sulfate Pb5O4SO4
lead oxide sulfate hydrate Pb4O3SO4.H2O

no apparent lines unassigned.