My technician and I have used the software EVA version 5.0.1.8, from SOCABIM, 
1999, with PDF files up to book 47. We were not able to identify all peaks. 
Our results are:

SMRR-1
Quartz and fluorapatite are certain, a phosphate phase is possible, either 
Arupite or Sousalite, and there is some possibility for the presence of Clinoclase.

SMRR-2
This was the most difficult to identify, we are not sure of the Cobalt oxide.

SMRR-3
We are not sure on this one either. Thalidomide is a possible phase.

SMRR-4
lead oxide and lead oxide sulphate are two phases probably present but there 
are missing peaks in our identification. So it is certain that we have, at 
least, another phase.