Below are my results for your powder xrd search match round robin. I am running Traces v5 search match software, and using the ICDD Powder Diffraction File Release 1999 ( Data sets 1-49 plus 70 - 86). Unfortunately, my software doesn't allow me to send you an electronic copy of the pattern and matches. I can post a paper copy if you need it. ...and my work is mainly to do with geological and industrial samples. I have been working with xrd for about 9 years, but have no experience with organic or pharmaceutical samples. My matches are as follows: Sample 1 smrr-1 quartz, SiO2 siderite, FeCO3 hydroxylapatite, Ca5(PO4)3(OH) gormanite, Fe3Al4(PO4)4(OH)6.2H2O Sample 2 smrr-2 stishovite, SiO2 quartz, SiO2 SiF4 SiO2 This is not a complete match by any means, and I would not be happy to give these results to a customer. I cannot identify the organic phase. Sample 3 smrr-3 thalidomide, C13H10N2O Again, this is not a complete match and there are other (unidentified) phases present. I have no experience with organic phase identification, so this is purely a results from the software and the chemistry provided. Sample 4 smrr-4 Litharge, PbO Lead oxide sulfate hydrate, Pb4O3So4.xH2O Lead oxide sulfate, Pb5O4SO4